Catalysts for halogenated hydrocarbon processing, their precursors and their preparation and use

ABSTRACT

A process is disclosed for changing the fluorine content of halogenated hydrocarbons containing from 1 to 6 carbon atoms, in the presence of a multiphase catalyst, which is characterized by preparing certain single phase solid catalyst precursors containing two metal components (e.g., a divalent component of Mn, Co, Zn, Mg and/or Cd and a trivalent component of Al, Ga, Cr and/or V) which have structures that collapse at about 600° C. or less; and producing said catalyst by heating the precursor to produce a multiphase composition wherein a phase containing one of the metal components is homogeneously dispersed with a phase containing the other metal component, and at least when the precursor contains no fluoride, contacting said multiphase composition with a vaporizable fluorine-containing fluorination compound at a temperature of from about 200° C. to 450° C. Also disclosed are single phase fluoride compositions having the formula MM&#39;F 5  (H 2  O) 2  wherein M is a divalent component selected from Mn, Co, Zn, Mg and/or Cd and M&#39; is a trivalent component selected from Al, Ga, Cr and/or V (provided that Cr is not more than about 10 atom percent of M&#39;); preparation of certain homogeneously dispersed multiphase catalyst compositions containing fluorides of those divalent and trivalent metal components; and certain homogeneously dispersed multiphase catalyst compositions containing fluorides of those divalent and trivalent metal components (provided that when Co is used another of said divalent elements is also used).

This application is a national filing under 35 USC 371 of International Application No. PCT/US95/0586, filed May 19, 1995 claiming priority of U.S. patent application Ser. No. 08/249,765 filed May 26, 1994 and issued as U.S. Pat. No. 5,559,069.

This application is a national filing under 35 USC 371 of International Application No. PCT/US95/0586, filed May 19, 1995 claiming priority of U.S. patent application Ser. No. 08/249,765 filed May 26, 1994 and issued as U.S. Pat. No. 5,559,069.

FIELD OF THE INVENTION

This invention relates to fluoride compositions and their preparation and use, and more particularly to fluoride catalysts, precursors for such catalysts, and preparation and use of such catalysts for processing halogenated hydrocarbons.

BACKGROUND

Numerous processes have been developed for changing the fluorine content of halogenated hydrocarbons. These include increasing the fluorine amount of halogenated hydrocarbons which are not fully fluorinated, decreasing the fluorine content of halogenated hydrocarbon containing fluorine, and redistributing the number of fluorine atoms among two or more halogenated hydrocarbon molecules which are not fully fluorinated.

Various catalysts have been proposed for use in facilitating processes such as hydrofluorination, hydrochlorination (i.e., fluorine substitution by chlorine) and disproportionation which involve halogenated hydrocarbons. See, e.g., L. E. Manzer et al., Adv. Catal. (39) pp. 329-350 (1993). The catalysts proposed include catalysts involving combinations of cations. For example, a well known class of catalysts includes metals supported on alumina or fluorinated alumina. Typically these materials are prepared by depositing a soluble salt of the metal on an alumina or aluminum fluoride support. While this method does provide a combination catalyst, the support material and the material deposited thereon are not uniformly mixed. Techniques such as coprecipitation which rely upon physical characteristics of individual components (e.g., solubility) also typically yield non-homogeneously dispersed products due to differences in physical and chemical properties of the components. There is an interest in developing means for more homogeneous dispersion of components of multiple cation catalysts which can be used for changing the fluorine content of halogenated hydrocarbons.

SUMMARY OF THE INVENTION

This invention provides a process for changing the fluorine content of halogenated hydrocarbons containing from 1 to 6 carbon atoms, in the presence of a multiphase catalyst. The process is characterized by (1) preparing a single phase solid catalyst precursor which has a structure that collapses at a temperature of about 600° C. or less and has the formula E_(u) E'_(1-u) Z_(v) (H₂ O)_(w) Y_(z) wherein E is at least one element selected from the group consisting of Group I through Group VIII metals of the Periodic Table, E' is at least one element other than the E elements selected from the group consisting of Group I through Group VIII metals of the Periodic Table, Z is at least one anion selected from fluoride, chloride, bromide, oxide and oxygen-containing groups which decompose at about 600° C., or less, Y is a cation which decomposes at about 600° C., or less, u is from 0.001 to 0.999, w is from 0 to about 20, z is from 0 to about 5, and v is selected to essentially balance the charge of said precursor; and (2) producing said catalyst by heating said single phase solid catalyst precursor to about 600° C. or less to produce a multiphase composition wherein a phase containing E is homogeneously dispersed with a phase containing E', and at least when said precursor contains no fluoride, contacting said multiphase composition with a vaporizable fluorine-containing fluorinating compound at a temperature of from about 200° C. to 450° C.

This invention further provides single phase fluoride compositions having the formula MM'F₅ (H₂ O)₂ wherein M is at least one divalent element selected from the group consisting of Mn, Co, Zn, Mg and Cd and M' is at least one trivalent element selected from the group consisting of Al, Ga, Cr and V, provided that Cr is not more than about 10 atom percent of M'. This invention also provides multiphase catalyst compositions consisting essentially of fluorides of at least one divalent element selected from the group consisting of Mn, Co, Zn, Mg and Cd, provided that when Co is used another of said divalent elements is also used, and at least one trivalent element selected from the group consisting of Al, Ga, Cr and V, provided that Cr is not more than about 10 atom percent of said trivalent elements, wherein phases of said divalent fluorides are homogeneously dispersed with phases of said trivalent fluorides. A homogeneously dispersed multiphase catalyst composition consisting essentially of fluorides of divalent Mn, Co, Zn, Mg and/or Cd and trivalent Al, Ga, Cr and/or V (provided that Cr is not more than about 10 atom percent of said trivalent elements) may be prepared in accordance with this invention by heating a corresponding single phase fluoride composition of the formula MM' F₅ (H₂ O)₂ or by heating a corresponding single phase fluoride composition of the formula NH₄ MM'F₆ (H₂ O), wherein M and M' are as defined above, to a temperature sufficient to substantially remove H₂ O (and NH₄ F, when NH₄ + is present) therein.

DETAILED DESCRIPTION

The catalytic process of this invention for changing the fluorine content of halogenated hydrocarbons containing from 1 to 6 carbon atoms employs a multiphase catalyst prepared in a manner which provides homogeneous dispersion of multiple metal components by preparing a decomposable single phase solid catalyst precursor and then converting the precursor to a multiple phase catalyst containing fluorine. A single phase catalyst precursor of the formula E_(u) E'.sub.(1-u) Z_(v) (H₂ O)_(w) Y_(z) may be prepared by conventional synthetic techniques (e.g., crystallization). E and E' represent different metal components selected from the Group I (e.g., Cu, K and Cs), Group II (e.g., Ca, Zn, Cd and Mg), Group III (e.g., Al, Y, Ga, La and Ce), Group IV (e.g., Ti, Zr and Sn), Group V (e.g., V, Nb and Bi), Group VI (e.g., Cr, Mo and Te), Group VII (e.g., Mn and Re), and Group VIII (e.g., Pd, Pt, Co, Ru, Rh and Ir) of the Periodic Table. (The Periodic Table of the Elements as listed in the CRC Handbook of Chemistry and Physics, 64th Edition (1983) is used herein to define the elemental groups.) For example, E may be a divalent metal component such as Mn, Co, Zn, Mg and/or Cd and E' may be a trivalent metal component such as Al, Ga, Cr and/or V. Normally, the ratio of the metal components, u:(1-u), should be between 1:999 and 999:1. Z represents an anion component which includes fluoride and/or anions capable of at least partial conversion to fluoride. Suitable Z anions include fluoride, chloride, bromide, oxide and decomposable oxygen-containing groups such as nitrate, carbonate and acetate. The precursor may also contain water molecules and/or decomposable cations such as ammonium. Typically, w, the ratio of water (when present) to total metal (E+E') is about 20, or less; and z, the ratio of decomposable cations (when present) to the total metal (E+E') is about 5, or less. Preferably, w is at least 1. Generally, v, the ratio of the anion component Z to the total metal (E+E') corresponds to the amount of anion required to balance the cation charge provided by the E, E' and Y components.

It will be evident that providing single phase precursors as described arranges the two components, E and E', in a structured arrangement where E and E' are closely connected through the Z, H₂ O and/or Y components. Various structures may be produced (e.g., orthorhombic or cubic). In any case, as a result of the arrangement of the components in the precursor, when the single phase structure collapses upon heating, uniformly interspersed phases of E and E' are formed. These are referred to herein as "homogeneously dispersed" phases.

It is desirable to convert the single phase precursor to multiphase composition at a moderately elevated temperature (e.g., about 600° C. or less). While some single phase structures are unstable and collapse upon heating, this conversion is ordinarily accomplished by decomposing the decomposable groups and/or removing water from the precursor. Accordingly, the decomposable oxygen-containing groups (when present) and the decomposable cations (when present) preferably decompose at about 600° C. or less. It is also desirable that water, when present, is substantially removed at about 600° C. or less.

The catalysts used for changing the fluorine content of halogenated hydrocarbons should contain fluoride (as a fluoride or in combination with other anions as in oxyfluorides). When the multiphase composition produced by heating the single phase precursor contains no fluoride, the chloride, bromide and/or oxide present may be at least partially converted to fluoride by contacting the multiphase composition with a vaporizable fluorine-containing fluorinating compound. Even when the multiphase composition produced by heating the single phase precursor does contain fluoride, together with other anions, a more active catalyst may often be achieved by contacting the multiphase composition with a vaporizable fluorine-containing fluorinating compound. Typically, where additional fluoride is desired, a multiphase composition is treated with a vaporizable fluorine-containing fluorinating compound such as HF, SF₄, COF₂, CCl₃ F, CCl₂ F₂, CHF₃ or CCl₂ FCClF₂, at elevated temperatures (e.g., at about 200° C. to about 450° C.) until the desired degree of fluorination is obtained (see, e.g., U.S. Pat. No. 4,902,838).

Included in this invention is a process for increasing the fluorine content of a saturated or olefinic compound having the formula C_(n) H_(a) F_(b) X_(c) where n is an integer from 1 to 6, a is an integer from 0 to 12, b is an integer from 0 to 13, c is an integer from 0 to 13, provided that c is at least 1 when the compound is saturated and each X is independently selected from Cl and Br, by reacting said compound with HF in the vapor phase; a process for decreasing the fluoride content of a saturated compound having the formula C_(m) H_(d) F_(e) X_(f) where m is an integer from 1 to 6, d is an integer from 0 to 4, e is an integer from 1 to 13, f is an integer from 0 to 12, and each X is independently selected from Cl and Br, by reacting said compound with HCl in the vapor phase; and a process for the disproportionation of a compound having the formula C_(p) H_(g) F_(h) Cl where p is an integer from 1 to 2, g is an integer from 1 to 3, and h is an integer from 1 to 4. These processes are respectively characterized by reacting the C_(n) H_(a) F_(b) X_(c) compound with HF, reacting the C_(m) H_(d) F_(e) X_(f) compound with HCl, and conducting the disproportionation of the C_(p) H_(g) F_(h) Cl compound, in the presence of a multiphase catalyst containing fluorine which has a phase containing E homogeneously dispersed with a phase containing E' and/or is prepared by heating the above defined single phase catalyst precursor of the formula E_(u) E'_(1-u) Z_(v) (H₂ O)_(w) Y_(z). Preferably, these processes are conducted in the presence of a multiphase catalyst composition consisting essentially of fluorides of at least one divalent element selected from the group consisting of Mn, Co, Zn, Mg, and Cd and at least one trivalent element selected from the group consisting of Al, Ga, Cr and V, provided that Cr is not more than about 10 atom percent of said trivalent elements, which have phases of said divalent fluorides homogeneously dispersed with phases of said trivalent fluorides and/or are prepared by heating a single phase fluoride compositions of the formula MM'F₅ (H₂ O)₂ or the formula NH₄ MM'F₆ (H₂ O) as defined herein.

Single-phase fluoride compositions of the formula MM'F₅ (H₂ O)₂ may be prepared by dissolving oxides or salts of M and M' (the relative amounts chosen so that the atomic ratio M:M' is essentially 1:1) in aqueous HF at room temperature and evaporating the solution to dryness (e.g., at a temperature of from about 100° C. to 130° C.). Preferably, the recovered solid is dried at about 110° C. for 12 hours. For example, quantities of reactants in the form of oxides, hydroxides, nitrates, fluorides and/or carbonates of M and M'0 which are chosen to provide the desired atomic ratio of M:M' can be individually dissolved in 48% aqueous HF and mixed (e.g., in a 500 ml Teflon® flask); the mixture can then be heated to about 100° C. to remove excess HF, (the HF vapors may be condensed and collected); and the residue can be recovered and dried at 110° C. in a vacuum drying oven for 12 hours. (Reference is also made to the technique for preparing iron-containing fluorohydrates containing divalent and trivalent cations as disclosed in P. Charpin et al., C. R. Acad. Sci. Paris, C280, 61-64 (1975), T. W. Balcerekm et al., J. Inorg. & Nucl. Chem., 40. 773 (1978), and Y. Laligant, et al., Chemica Scripta, 28, 101 (1988).)

Alternatively, the single-phase fluoride compositions can be prepared by direct precipitation from aqueous chloride solutions of divalent M and trivalent M', using HF as a precipitant. The precipitate is filtered and washed with distilled water and dried at about 110° C. For example, quantities of the reactants in the form of chlorides of M and M' which are chosen to provide the desired atomic ratio of M:M' and are dissolved in distilled water and mixed in a container (e.g., in a Teflon® beaker); a ten-fold excess of 48% aqueous HF may be added to the above solution under stirring; and the precipitate formed may be recovered by filtration, washed with distilled water and dried at about 110° C. for about 12 hours.

The lattice parameters of these single-phase fluoride compositions are determined from x-ray diffraction powder patterns. The thermogravimetric analysis of these fluorides from room temperature to 600° C. shows weight loss corresponding to 2 moles of H₂ O per mole of MM'F₅ (H₂ O)₂.

Of note are embodiments where M is from 1 to 99 atom percent of one divalent metal (e.g., Zn or Co) with the remainder being one or more of the other divalent metals. Examples include embodiments where M comprises zinc and cobalt and where M comprises zinc and magnesium. Also of note are embodiments where M' is from 1 to 99 atom percent of one trivalent metal (e.g., Al or Ga) with the remaining being one or more of the other trivalent metals. Examples include embodiments where M' comprises aluminum and chromium.

The single-phase fluoride compositions of the formula MM'F₅ (H₂ O)₂ may be used to prepare multiphase compositions consisting essentially of fluorides of at least one divalent element selected from the group consisting of Mn, Co, Zn, Mg and Cd and at least one trivalent element selected from the group consisting of Al, Ga, Cr and V suitable for use as catalysts. This may be accomplished by heating these single-phase compositions at about 300° C. to 350° C. for a suitable period (e.g., typically 1 hour or more). The multiphase catalysts obtained by this method are characterized by having homogeneously dispersed fluorides of the divalent and trivalent elements. It will be understood that as H₂ O is removed from these single phase compositions, the crystal structure of the single phase composition collapses, resulting in the formation of multiple phases of metal fluorides.

Homogeneously dispersed multiphase compositions suitable for use as catalysts may also be prepared from single-phase fluoride compositions having the formula NH₄ MM'F₆ (H₂ O). This may be accomplished by heating these single phase compositions at about 400° C. to 450° C. for a suitable period (typically 1 hour or more). The multiphase catalysts obtained by this method are similar to those obtained from MM'F₅ (H₂ O)₂ and are characterized by having homogeneously dispersed divalent metal fluoride and trivalent metal fluoride phases. Compositions of the formula NH₄ MM'F₆ (H₂ O) may be prepared by precipitation of the compositions from aqueous chloride solutions of the metals and ammonium using aqueous HF as the precipitant. It will be understood that as H₂ O and NH₄ F are removed from these single phase compositions, the crystal structure of the single phase composition collapses, resulting in the formation multiple phases of metal fluorides.

The catalyst preparation methods of this invention include a method of preparing a multiphase catalyst composition consisting essentially of fluorides of at least one divalent metal selected from the group consisting of Mn, Co, Zn, Mg and Cd and at least one trivalent metal selected from the group consisting of Al, Ga, Cr and V, wherein when Co is present another of said divalent metals is also present and Cr is not more than about 10 mole percent of said trivalent metals. These embodiments are characterized by heating a single phase fluoride composition of the formula MM'F₅ (H₂ O )₂ or the formula NH₄ MM'F₆ (H₂ O) when M is at least one divalent element selected from the group consisting of Mn, Co, Zn, Mg and Cd, provided that when Co is used another of said divalent elements is also used and M' is at least one trivalent element selected from the group consisting of Al, Ga, Cr and V, provided that Cr is not more than 10 atom percent of said trivalent elements at a temperature sufficient to substantially remove H₂ O , and NH₄ F when NH₄ is present, bound in said single phase fluoride composition. The catalysts of this invention include multiphase catalyst compositions consisting essentially of fluorides of at least one divalent element and at least one trivalent element prepared in accordance with these embodiments; and these catalysts may be used for the process for increasing the fluorine content of compounds of the formula C_(n) H_(a) F_(b) X_(c), the process for decreasing the fluorine content of compounds of the formula C_(m) H_(d) F_(e) X_(f), and for the process for the disproportionation of compounds of the formula C_(p) H_(g) F_(h) Cl, as described herein.

Of note are embodiments of multiphase catalyst compositions derived from MAlF₅ (H₂ O)₂ or NH₄ MAlF₆ (H₂ O) (i.e., the trivalent metal, M', is aluminum) where the trivalent fluoride is β-aluminum fluoride.

Homogeneously dispersed multiphase catalysts of fluorides of divalent and trivalent elements may be used in accordance with this invention in a process for increasing the fluorine content of compounds of the formula C_(n) H_(a) F_(b) X_(c), having from 1 to 6 carbon atoms and when the compound is saturated at least one X (i.e., Cl or Br), by reacting said compounds with HF in the vapor phase in the presence of such catalysts. Of note are embodiments where X is Cl. Suitable catalysts for this reaction include compositions consisting essentially of fluorides of at least one divalent element selected from the group consisting of Mn, Co, Zn, Mg, and Cd homogeneously dispersed with fluorides of at least one trivalent element selected from the group consisting of Al, Ga, Cr and V, provided that Cr is not more than about 10 atom percent of said trivalent elements.

The reaction of said compounds of the formula C_(n) H_(a) F_(b) X_(c) with HF in the presence of the catalysts of the instant invention is typically conducted at about 150° C. to 500° C., preferably for saturated compounds at about 175° C. to 400° C., and more preferably for saturated compounds at about 200 C. to about 350° C., with a contact time of about 1 to about 120 seconds, preferably about 5 to about 60 seconds. The amount of HF ordinarily should be at least a stoichiometric amount. Typically, the molar ratio of HF to the said compounds of the formula C_(n) H_(a) F_(b) X_(c) can range from about 1:1 to about 100:1, preferably about 2:1 to 50:1, and more preferably about 3:1 to 10:1. In general, with a given catalyst composition, the higher the temperature and the longer the contact time, the greater is the conversion to fluorinated products. The above variables can be balanced, one against the other, so that the formation of higher fluorine substituted products is maximized.

Examples of olefinic compounds which may be reacted with HF include CHCl═CCl₂, CCl₂ ═CCl₂, CCl₃ CCl═CClCCl₃, CCl₂ ═CH₂, CHF═CF₂, CF₂ ═CH₂ and CF₂ ═CFCl. Of note is a catalytic process for producing 2-chloro-1,1,1-trifluoroethene (HCFC-133a) by the fluorination of a trihaloethene of the formula CX₂ ═CHCl wherein each X is chlorine or fluorine. Starting materials include trichloroethene, 1,2-dichlorofluoroethene and 1-chloro-2,2-difluoroethene. Trichloroethene is preferred. HCFC-133a is produced by reacting the above unsaturated compounds with HF in the vapor phase in the presence of the catalysts of this invention. The reaction of the above trihaloethenes with HF in the presence of the catalysts of the instant invention is preferably conducted at about 150° C. to 350° C., more preferably about 175° C. to 250° C. Oxygen may be added, if desired.

Also of note is a catalytic process for producing 2,2-dichloro-1,1,1-trifluoroethane (CHCl₂ CF₃, i.e., HCFC-123), 1,1,1,2-tetrafluorochloroethane (CHClFCF₃, i.e., HCFC-124) and pentafluoroethane (CHF₂ CF₃, i.e., HFC-125) by the fluorination of a tetrahaloethene of the formula C₂ Cl_(4-x) F_(x), wherein x equals 0 to 3. Starting materials include CCl₂ ═CCl₂, CClF═CCl₂, CClF═CClF CF₂ ═CCl₂, and CF₂ ═CClF. Tetrachloroethene is preferred. HCFC-123, HCFC-124 and/or HFC-125 is produced by reacting the above unsaturated compounds with HF in the vapor phase in the presence of the catalysts of this invention.

Examples of saturated compounds which may be reacted with HF include CH₂ Cl₂, CHCl₃, C₂ Cl₆, C₂ Cl₅ F, C₂ Cl₄ F₂, C₂ Cl₃ F₃, C₂ Cl₂ F₄, C₂ ClF₅, C₂ HCl₅, C₂ HCl₄ F, C₂ HCl₃ F₂, C₂ HCl₂ F₃, and C₂ HClF₄. Of note are catalytic processes for reacting 1,1,1-trichloro-2,2,2-trifluoroethane (i.e., CCl₃ CF₃, CFC-113a), or reacting dichloromethane, with HF, in the vapor phase in the presence of the catalysts of this invention. For the reaction of CFC-113a with HF to yield CCl₂ FCF₃ (CFC-114a), the HF:CCl₃ CF₃ ratio can vary widely. The HF:CFC-113a ratio should be at least stoichiometric but preferably can vary from about 2:1 to about 10:1.

For the reaction of dichloromethane to yield difluoromethane (CH₂ F₂, HFC-32), the molar ratio of HF to CH₂ Cl₂ preferred ranges from about 1:1 to about 10:1. The reaction temperature normally ranges from about 180° C. to about 375°C. (e.g., from about 200° C. to about 350° C.)

Homogeneously dispersed multiphase catalysts of fluorides of divalent and trivalent elements may be used in accordance with this invention in a process for decreasing the fluorine content of a saturated compound having the formula C_(m) H_(d) F_(e) X_(f) having from 1 to 6 carbon atoms and at least one fluorine, by reacting such compounds with HCl in the vapor phase in the presence of such catalysts. Suitable catalysts for this reaction include compositions consisting essentially of fluorides of at least one divalent element selected from the group consisting of Mn, Co, Zn, Mg, and Cd homogeneously dispersed with fluorides of at least one trivalent element selected from the group consisting of Al, Ga, Cr, and V, provided that Cr is not more than about 10 atom percent of said trivalent elements.

The reaction of said compounds of the formula C_(m) H_(d) F_(e) X_(f) with HCl in the presence of the catalysts of the instant invention is typically conducted at about 225° C. to 450° C., preferably from about 250° C. to 350° C. The amount of HCl should be at least a stoichiometric amount. Generally, the molar ratio of HCl to the C_(m) H_(d) F_(e) X_(f) compound ranges from about 2:1 to about 100:1, preferably about 3:1 to 50:1, and more preferably about 5:1 to 20:1.

Chlorine may be present in some process embodiments, either as an initial reactant or as an in-situ formed product.

Oxygen may be added if desired. The amount of oxygen present during the contacting step relative to the molar concentration of the C_(m) H_(d) F_(e) X_(f) can also vary but will generally range from 0.001 to 1.0 moles. The oxygen may be fed to the reactor as such or may be diluted with an inert gas such as nitrogen, helium or argon. The source of the oxygen may also be air containing molecular oxygen.

In general, with a given catalyst composition, the higher the temperature and the longer the contact time, the greater is the conversion of the C_(m) H_(d) F_(e) X_(f) compound to chlorinated products. The above variables can be balanced, one against the other, so that the reaction is optimized.

Examples of saturated compounds that can be reacted with HCl include C₂ Cl₄ F₂, C₂ Cl₃ F₃, C₂ Cl₂ F₄, C₂ ClF₅, CH₂ FCF₃, CHF₃, CHF₂ CF₃, CH₃ CF₃, CH₃ CHF2, CHCl₂ F, CHClF₂, CHCl₂ CF₃, CHClFCF₃, CH₂ ClCF₃, CH₃ ClF₂, CHBrF₂ and CHBrFCF₃. Of note is a process for selectively reacting 1,1-dichloro-1,2,2,2-tetrafluoroethane (CCl₂ FCF₃) with HCl in the presence of its isomer, 1,2-dichloro-1,1,2,2-tetrafluoroethane (CClF₂ CClF₂) in the vapor phase in the presence of the catalyst of this invention. The process is especially useful for enriching CClF₂ CClF₂ from initial mixtures wherein the CCl₂ FCF₃ content is equal to or greater than the CClF₂ CClF₂ content. Preferably, the fraction of total C₂ Cl₂ F₄ which is CCl₂ FCF₃ is reduced by at least 25%. The initial mixture may consist essentially of C₂ Cl₂ F₄ isomers, or may contain other compounds which do not interfere with the selective reaction of CCl₂ FCF₃. Typically, the reaction is controlled to provide CCl₃ CF₃ as the major chlorination product of CCl₂ FCF₃. The reaction of mixtures of CClF₂ CClF₂ and CCl₂ FCF₃ with HCl in the presence of the catalysts of the instant invention is preferably conducted at about 250° C. to 350° C., with a contact time of about 1 to about 120 seconds, preferably about 5 to about 60 seconds.

The reaction products are separated by conventional techniques, such as distillation. Some of the reaction products will have desired properties for commercial use. For example CCl₃ CF₃ (CFC-113a) can be used to prepare CFC-114a which can then be converted to CH₂ FCF₃ (HFC-134a) by hydrodechlorination. Others, such as CCl₂ ═CCl₂ can be recycled back to reactors which are being used for the synthesis of halofluorocarbons.

Homogeneously dispersed multiphase catalysts of fluorides of divalent and trivalent elements may be used in accordance with this invention in a catalytic process for the disproportionation of hydrochlorofluorocarbons of the formula, C_(p) H_(g) F_(h) Cl having from 1 to 2 carbon atoms, at least one hydrogen and at least one fluorine, to produce hydrofluorocarbons. Suitable catalysts for this reaction include compositions consisting essentially of fluorides of at least one divalent element selected from the group consisting of Mn, Co, Zn, Mg, and Cd homogeneously dispersed with fluorides of at least one trivalent element selected from the group consisting of Al, Ga, Cr, and V, provided that Cr is not more than about 10 atom percent of said trivalent elements.

Suitable hydrochlorofluorocarbons for disproportionation include CH₂ ClF, CH₃ CClF₂, and CHClFCF₃. The products of the disproportionation reactions are respectively, CH₂ F₂ and CH₂ Cl₂, CH₃ CF₃ and CH₂ ═CCl₂, and CHCl₂ CF₃ and CHF₂ CF₃.

Reactions for changing the fluorine content of a halogenated hydrocarbon (e.g., the reaction of the compounds of the formula C_(n) H_(a) F_(b) X_(c) with HF, the reaction of the compounds of the formula C_(m) H_(d) F_(e) X_(f) with HCl and the disproportionation of the compounds of the formula C_(p) H_(g) F_(h) Cl) may be conducted in any suitable reactor, including fixed and fluidized bed reactors. The reaction vessel should be constructed from materials which are resistant to the corrosive effects of hydrogen fluoride and hydrogen chloride such as Inconel™ nickel alloy and Hastelloy™ nickel alloy.

Pressure is not critical for these reactions. Atmospheric and superatmospheric pressures are the most convenient and are therefore preferred.

The reaction products may be separated by conventional techniques such as distillation. It is noted that many halogenated hydrocarbon products of the above reactions form azeotropes with HF, HCl, or other halogenated hydrocarbons.

The homogeneously dispersed multiphase compositions obtained herein from single phase MM'F₅ (H₂ O)₂ or NH₄ MM'F₆ (H₂ O) are also useful for preparing initiators for telomerization of polyfluoroalkyliodides with polyfluoroolefins. For example, granulated compositions containing AlF₃ together with either MnF₂ or CoF₂ can respectively be fluorinated with elemental fluorine to compositions containing AlF₃ together with either MnF₃ or CoF₃, and these resulting compositions can be used as initiators for the reaction of tetrafluoroethylene with C₅ F₁₃ I or C₂ F₅ I to produce telomeric perfluoroalkyl-iodides. Reference is made to U.S. patent application Ser. No. 08/249,311, the priority application for U.S. Pat. No. 5,574,193. for further discussion of such telomerizations.

Practice of the invention will become further apparent from the following non-limiting Examples.

EXAMPLES 1-10

Examples 1-10 were carried out using essentially the same procedure.

To make a composition having the formula MM'F₅ (H₂ O)₂, quantities of hydroxides, oxides, fluorides, and/or carbonates of M and M' corresponding to a M:M' ratio of 1:1 were dissolved separately in 48% aqueous HF and mixed together in a Teflon® container and the solution was evaporated to dryness. The specific quantities used in each Examples are shown in Table I. In each instance the residue or solid was recovered, ground to a powder, and dried at about 110° C. for about 12 hours.

The x-ray diffraction pattern of each of the products showed that the product was essentially a single phase. The orthorhombic lattice parameters of the products were determined from the x-ray diffraction powder patterns and are shown in Table II.

The compositions of Examples 1-5 were heated to from 300° C. to 350° C. for from 3 to 12 hours and the X-ray diffraction patterns of the resulting products showed the presence of MF₂ (M=Zn, Co, Mn, Mg or Cd) and β-AlF3.

EXAMPLES 11-15

Zn_(x) Co_(y) AlF₅ (H₂ O)₂ !

To make a composition of having the formula Zn_(x) Co_(y) AlF₅ (H₂ O)₂ where x is from 0.02 to 0.90 and y is from 0.10 to 0.98 (and x+y=1.00) quantities of oxides or hydroxides of Zn, Co or Al taken in the ratio Zn:Co:Al=x:y:1.0 were dissolved in 48% aqueous HF and mixed together in a Teflon® container and the solution was evaporated to dryness. The specific quantities used are shown in Table I. In each instance the residue or solid was recovered, ground to a powder, and dried at 110° C. for about 12 hours.

The x-ray diffraction pattern of each of the products showed that the product was essentially a single phase. The orthorhombic lattice parameters of the products were determined from the x-ray diffraction powder patterns and are shown in Table II.

The compositions were heated to 300° C. to 350° C. for 3 to 12 hours and the X-ray diffraction patterns of the ing products showed the presence of MF₂ (M=Zn, Co) and β-AlF3.

                                      TABLE I                                      __________________________________________________________________________                         TRIVALENT METAL                                                                           DIVALENT METAL                                  EXAMPLE                                                                               COMPOSITION  REACTANT   REACTANT                                        __________________________________________________________________________     1      ZnAlF.sub.5 (H.sub.2 O).sub.2                                                               12.480 g Al(OH).sub.3.sup.(a)                                                             13.0192 g ZnO.sup.(d)                           2      CoAlF.sub.5 (H.sub.2 O).sub.2                                                               2.3400 g Al(OH).sub.3.sup.(a)                                                             2.7885 g Co(OH).sub.2.sup.(e)                   3      MnAlF.sub.5 (H.sub.2 O).sub.2                                                               2.3400 g Al(OH).sub.3.sup.(a)                                                             3.4485 g MnCO.sub.3.sup.(f)                     4      MgAlF.sub.5 (H.sub.2 O).sub.2                                                               0.7800 g Al(OH).sub.3.sup.(a)                                                             0.5832 g Mg(OH).sub.2.sup.(g)                   5      CdAlF.sub.5 (H.sub.2 O).sub.2                                                               0.7800 g Al(OH).sub.3.sup.(a)                                                             1.5044 g CdF.sub.2.sup.(h)                      6      ZnGaF.sub.5 (H.sub.2 O).sub.2                                                               0.9372 g Ga.sub.2 O.sub.3.sup.(b)                                                         0.8137 g ZnO.sup.(d)                            7      MnGaF.sub.5 (H.sub.2 O).sub.2                                                               0.9372 g Ga.sub.2 O.sub.3.sup.(b)                                                         1.1495 g MnCO.sub.3.sup.(f)                     8      CdGaF.sub.5 (H.sub.2 O).sub.2                                                               0.0372 g Ga.sub.2 O.sub.3.sup.(b)                                                         1.5044 g CdF.sub.2.sup.(h)                      9      ZnVF.sub.5 (H.sub.2 O).sub.2                                                                0.7494 g V.sub.2 O.sub.3.sup.(c)                                                          0.8137 g ZnO.sup.(d)                            10     MnVF.sub.5 (H.sub.2 O).sub.2                                                                0.7494 g V.sub.2 O.sub.3.sup.(c)                                                          1.1495 g MnCO.sub.3.sup.(f)                     11     Zn.sub.0.1 Co.sub.0.9 AlF.sub.5 (H.sub.2 O).sub.2                                           7.8000 g Al(OH).sub.3.sup.(a)                                                             0.8137 g ZnO.sup.(d) +                                                         8.3600 g Co(OH).sub.2.sup.(e)                   12     Zn.sub.0.9 Co.sub.0.1 AlF.sub.5 (H.sub.2 O).sub.2                                           7.8000 g Al(OH).sub.3.sup.(a)                                                             7.3233 g ZnO.sup.(d) +                                                         0.9295 g Co(OH).sub.2.sup.(e)                   13     Zn.sub.0.02 Co.sub.0.98 AlF.sub.5 (H.sub.2 O).sub.2                                         7.800 g Al(OH).sub.3.sup.(a)                                                              0.1627 g ZnO.sup.(d) +                                                         9.1091 g Co(OH).sub.2.sup.(e)                   14     Zn.sub.0.04 Co.sub.0.96 AlF.sub.5 (H.sub.2 O).sub.2                                         7.800 g Al(OH).sub.3.sup.(a)                                                              0.4882 g ZnO.sup.(d) +                                                         8.9232 g Co(OH).sub.2.sup.(e)                   15     Zn.sub.0.06 Co.sub.0.94 AlF.sub.5 (H.sub.2 O).sub.2                                         7.800 g Al(OH).sub.3.sup.(a)                                                              0.4882 g ZnO.sup.(d) +                                                         8.7373 g Co(OH).sub.2.sup.(e)                   __________________________________________________________________________      .sup.(a) Tech. grade Al(OH).sub.3 from Alfa Inorganics                         .sup.(b) >99.9% Ga.sub.2 O.sub.3 from Johnson & Matthey Company                .sup.(c) >99.9% V.sub.2 O.sub.3 from Johnson & Matthey Company                 .sup.(d) General reagent ZnO from E. Merck                                     .sup.(e) 99% Co(OH).sub.2 from Aldrich Chemical Company                        .sup.(f) Tech. grade MnCO.sub.3 from Alfa Inorganics                           .sup.(g) >95% Mg(OH).sub.2 from Aldrich Chemical Company                       .sup.(h) 99.99% CdF.sub.2 from Aldrich Chemical Company                  

                  TABLE II                                                         ______________________________________                                         Lattice Parameters of M.sup.2+ M'.sup.3+ F.sub.5 (H.sub.2 O).sub.2             Compositions                                                                   EX-                   a (nm)   b (nm) c (nm)                                   AMPLE COMPOSITION     (±0.0002)                                                                            (±0.0004)                                                                          (±0.0002)                             ______________________________________                                         1     ZnAlF.sub.5 (H.sub.2 O).sub.2                                                                  0.7141   1.0307 0.6645                                   2     CoAlF.sub.5 (H.sub.2 O).sub.2                                                                  0.7193   1.0353 0.6608                                   3     MnAlF.sub.5 (H.sub.2 O).sub.2                                                                  0.7229   1.0487 0.6816                                   4     MgAlF.sub.5 (H.sub.2 O).sub.2                                                                  0.7057   1.0126 0.6796                                   5     CdAlF.sub.5 (H.sub.2 O).sub.2                                                                  0.7331   1.0639 0.6829                                   6     ZnGaF.sub.5 (H.sub.2 O).sub.2                                                                  0.7380   1.0600 0.6584                                   7     MnGaF.sub.5 (H.sub.2 O).sub.2                                                                  0.7471   1.0735 0.6720                                   8     CdGaF.sub.5 (H.sub.2 O).sub.2                                                                  0.7603   1.0875 0.6718                                   9     ZnVF.sub.5 (H.sub.2 O).sub.2                                                                   0.7486   1.0756 0.6589                                   10    MnVF.sub.5 (H.sub.2 O).sub.2                                                                   0.7607   1.0912 0.6728                                   11    Zn.sub.0.1 Co.sub.0.9 AlF.sub.5 (H.sub.2 O).sub.2                                              0.7174   1.0314 0.6646                                   12    Zn.sub.0.9 Co.sub.0.1 AlF.sub.5 (H.sub.2 O).sub.2                                              0.7146   1.0310 O.6645                                   13    Zn.sub.0.02 Co.sub.0.98 AlF.sub.5 (H.sub.2 O).sub.2                                            0.7152   1.0299 0.6589                                   14    Zn.sub.0.04 Co.sub.0.96 AlF.sub.5 (H.sub.2 O).sub.2                                            0.7157   1.0306 0.6590                                   15    Zn.sub.0.06 Co.sub.0.94 AlF.sub.5 (H.sub.2 O).sub.2                                            0.7172   1.0322 0.6167                                   ______________________________________                                          a, b, c are lattice parameters of an orthorhombic unit cell              

EXAMPLE 16

NH₄ MgAlF₆.H₂ O!

To make a composition having the formula NH₄ MgAlF₆.H₂ O quantities of NH₄ Cl (0.5349 g), MgCl₂.6H₂ O (2.0330 g) and AlCl₃.6H₂ O (2.3980 g) corresponding to a mole ratio of 1:1:1 were dissolved in distilled water in a Teflon® beaker. To the solution was added 48% aqueous HF until the precipitation was complete. The white solid formed was filtered and washed with deionized water and dried at 110° C. for 12 hours.

The x-ray diffraction pattern of the product showed that the product was essentially single phase. The cubic lattice parameter of the product were determined from the x-ray diffraction powder pattern (a=0.99608 nm).

The composition was heated to 450° C. for 3 to 12 hours and the X-ray of the resulting product showed the presence of MgF₂ and β-AlF₃.

General Procedure for Examples 17-32

A reactor, 11" (27.9 cm)×1/2" (1.3 cm) Inconel™ nickel alloy tube containing an internal thermowell, containing 12 to 15 mL of catalyst (10 to 14 mesh, i.e., 1.7 to 1.3 mm), was heated in a fluidized sandbath. The feed to the reactor was measured through mass flow controllers, or when liquids were used, they were metered by liquid metering pumps. The liquid feeds were vaporized and mixed with HF or nitrogen as appropriate, prior to entering the reactor. All experiments were performed at ambient pressure. The products from the reactor were analysed by on line GC/MS. The results are shown in the tables included with the examples. In the tables HRS. is hours and R.T. is the reaction temperature. The CH₂ Cl₂ feeds contained about 99% CH₂ Cl₂, and about 1% F31. The molar ratio of HF:CH₂ Cl₂ was about 4:1 and the contact time was about 15 seconds in all cases. The F113a feeds contained about 98.6% F113a and about 1.4% F114a. The molar ratio of HF:F113a was about 2:1 and the contact time was about 30 seconds in all cases.

EXAMPLE 17 Fluorination of Methylene Chloride

    ______________________________________                                         MnF.sub.2 /β-AlF.sub.3 (Product of Example 3; 12.5 g, 12 mL)              CH.sub.2 Cl.sub.2 + HF → CH.sub.2 ClF + CH.sub.2 F.sub.2                             Mole %                                                            HRS.      R.T. (°C.)                                                                       F32        F31  CH.sub.2 Cl.sub.2                           ______________________________________                                         2.5       250      1.3        8.2  90.6                                        3.5       275      1.4        8.6  90.1                                        ______________________________________                                          F32 is CH.sub.2 F.sub.2 -                                                      F31 is CH.sub.2 ClF                                                      

EXAMPLE 18 Fluorination of F113a

    ______________________________________                                         MnF.sub.2 /β-AlF.sub.3 (Product of Example 3; 12.5 g, 12 mL)              CCl.sub.3 CF.sub.3 + HF → CCl.sub.2 FCF.sub.3                                             Mole %                                                       HRS.        R.T. (°C.)                                                                       F114a         113a                                        ______________________________________                                         0.5         275      2.4           97.5                                        2.0         300      2.5           97.4                                        2.5         325      2.5           97.4                                        3.0         350      2.9           97.0                                        ______________________________________                                          F114a is CCl.sub.2 FCF.sub.3 -                                                 F113a is CCl.sub.3 CF.sub.3 -                                            

EXAMPLE 19 Fluorination of F113a

    ______________________________________                                         ZnF.sub.2 /β-AlF.sub.3 (Product of Example 1; 16.1 g, 15 mL)                           Mole %                                                            HRS.      R.T. (°C.)                                                                       F114a       F113 113a                                       ______________________________________                                         1.0       200      2.4         0.1  97.4                                       2.0       250      3.3         0.1  96.6                                       3.0       300      6.4         0.1  93.5                                       4.0       350      11.5        0.0  88.4                                       5.0       350      9.9         0.0  90.0                                       ______________________________________                                          F113 is CCl.sub.2 FCClF.sub.2 -                                          

EXAMPLE 20 Fluorination of Methylene Chloride

    ______________________________________                                         ZnF.sub.2 /β-AlF.sub.3 (Product of Example 1; 16.1 g, 15 mL)                           Mole %                                                            HRS.      R.T. (°C.)                                                                       F32        F31  CH.sub.2 Cl.sub.2                           ______________________________________                                         1.5       300      16.5       16.1 67.4                                        ______________________________________                                    

EXAMPLE 21 Fluorination of Methylene Chloride

    ______________________________________                                         ZnF.sub.2 /CoF.sub.2 /β-AlF.sub.3 (Product of Example 11; 15.0 g, 15      mL)                                                                                         Mole %                                                            HRS.      R.T. (°C.)                                                                       F32        F31  CH.sub.2 Cl.sub.2                           ______________________________________                                         5.5       250      51.9       12.5 35.6                                        7.0       275      46.6       13.9 39.5                                        ______________________________________                                    

EXAMPLE 22 Fluorination of F113a

    ______________________________________                                         ZnF.sub.2 /CoF.sub.2 /β-AlF.sub.3 (Product of Example 11; 15.0 g, 15      mL)                                                                                              Mole %                                                       HRS.        R.T. (°C.)                                                                       F114a         113a                                        ______________________________________                                         1.5         200      3.2           96.6                                        2.0         225      4.6           95.1                                        2.5         250      6.2           93.4                                        3.0         275      8.8           91.0                                        3.5         300      13.9          79.6                                        5.5         350      23.2          76.4                                        ______________________________________                                    

EXAMPLE 23 Fluorination of F113a

CoF₂ /β-AlF₃ (15.0 g, 15 mL)

The catalyst used in this example was prepared in a manner similar to the procedure in A. Demsar et al., Thermochemica Acta (92), 665-668 (1985). (NH₃)₆ CoCl₃ of >95% purity (3740 g) and AlCl₃.6H₂ O (12.0715 g), in a 1:1 mole ratio, were weighed into separate Teflon® beakers and dissolved in distilled water (50 mL). 48% HF (100 mL) was added to the cobalt chloride containing solution. The AlCl₃ solution was added to the cobalt chloride solution with stirring. The yellow precipitate obtained was filtered and dried at 110° C. for about 12 hours. The X-ray diffraction pattern showed the formation of a single phase material with a cubic lattice parameter of 0.986 nm. The structural formula of the single phase is (NH₃)₆ CoAlF₆.

The above single phase composition was heated to 350° C. for about 12 hours and the X-ray diffraction pattern of the product showed the presence of CoF₂ /β-AlF₃. The product was granulated to form 1.3 to 1.7 mm size particles, and used for fluorination of F113a, with the following results.

    ______________________________________                                                           Mole %                                                       HRS.        R.T. (°C.)                                                                       F114a         113a                                        ______________________________________                                         1.0         200      1.5           98.4                                        2.0         250      1.6           98.4                                        3.5         300      1.6           98.3                                        4.5         350      1.9           97.9                                        ______________________________________                                    

EXAMPLE 24 Fluorination of Methylene Chloride

    ______________________________________                                         CoF.sub.2 /β-AlF.sub.3 (15.0 g, 15 mL)                                    The catalyst used was prepared in the same manner                              as that used in Example 23.                                                                 Mole %                                                            HRS.      R.T. (°C.)                                                                       F32        F31  CH.sub.2 Cl.sub.2                           ______________________________________                                         1.0       300      3.5        8.5  88.0                                        ______________________________________                                    

EXAMPLE 25 Fluorination of F113a

    ______________________________________                                         ZnF.sub.2 /CoF.sub.2 /β-AlF.sub.3 (Product of Example 13, 13.7 g, 15      mL)                                                                                              Mole %                                                       HRS.        R.T. (°C.)                                                                       F114a         113a                                        ______________________________________                                         1.0         250      13.9          86.1                                        2.0         275      19.9          80.0                                        2.5         300      28.7          71.1                                        3.0         325      31.8          68.1                                        4.0         350      38.0          61.9                                        ______________________________________                                    

EXAMPLE 26 Fluorination of Methylene Chloride

    ______________________________________                                         ZnF.sub.2 /CoF.sub.2 /β-AlF.sub.3 (Product of Example 13, 13.7 g, 15      mL)                                                                                         Mole %                                                            HRS.      R.T.(°C.)                                                                        F32        F31  CH.sub.2 Cl.sub.2                           ______________________________________                                         0.5       175      29.7       12.8 57.5                                        1.5       200      42.9       11.1 45.9                                        2.5       225      51.2       11.9 37.1                                        3.0       250      54.8       12.4 32.7                                        ______________________________________                                    

EXAMPLE 27 Fluorination of F113a

    ______________________________________                                         ZnF.sub.2 /CoF.sub.2 /β-AlF.sub.3 (Product of Example 12, 15.0 g, 15      mL)                                                                                              Mole %                                                       HRS.     R.T. (°C.)                                                                             F114a   113a                                           ______________________________________                                         1.0      250            4.3     95.6                                           2.0      275            5.3     94.6                                           2.5      300            7.0     92.9                                           3.0      325            8.9     91.0                                           4.0      350            11.6    88.3                                           ______________________________________                                    

EXAMPLE 28 Fluorination of Methylene Chloride

    ______________________________________                                         ZnF.sub.2 /CoF.sub.2 /β-AlF.sub.3 (Product of Example 12, 15.0 g, 15      mL)                                                                                         Mole %                                                            HRS.      R.T.(°C.)                                                                        F32        F31  CH.sub.2 Cl.sub.2                           ______________________________________                                         2.0       250      10.5       13.9 75.6                                        3.0       275      17.2       15.6 67.1                                        ______________________________________                                    

    ______________________________________                                         Catalyst Comparisons                                                                        Mole %                                                            Ex.       R.T.(°C.)                                                                        F32        F31  CH.sub.2 Cl.sub.2                           ______________________________________                                         20        300      16.5       16.1 67.4                                        24        300      3.7        8.7  87.6                                        21        250      52.0       12.6 35.4                                        17        250      1.2        8.1  90.5                                        26        250      54.8       12.4 32.7                                        28        250      10.5       13.9 75.6                                        ______________________________________                                    

    ______________________________________                                         Catalyst Comparisons at 350° C.                                                       Mole %                                                           Ex.             F114a   113a                                                   ______________________________________                                         19              9.9     90.0                                                   23              1.9     97.9                                                   22              23.2    76.4                                                   18              2.9     97.0                                                   25              38.0    61.9                                                   27              11.6    88.3                                                   ______________________________________                                    

EXAMPLE 29 Fluorination of TCE

    __________________________________________________________________________     ZnF.sub.2 /CoF.sub.2 /β-AlF.sub.3 (Product of Example 11; 15.0 g, 15      mL)                                                                                      Mole %                                                               HRS.                                                                               R.T. (°C.)                                                                    F23 F133a                                                                               F1121                                                                               F132b                                                                               F1121                                                                               F131a                                                                               TCE                                     __________________________________________________________________________     1.5 150   0.0 2.1  1.0  8.7  2.0  0.5  85.6                                    2.5 175   0.0 5.2  1.8  12.7 2.6  0.5  77.5                                    3.5 200   0.0 8.8  1.8  10.4 2.6  0.4  75.8                                    4.0 225   0.1 9.6  1.8  6.4  2.7  0.4  78.9                                    5.0 250   0.1 7.6  1.9  3.3  3.0  0.3  83.5                                    __________________________________________________________________________      F23 is CHF.sub.3 -                                                             F133a is CH.sub.2 ClCF.sub.3 -                                                 F1121 is CFCl═CHCl (both isomers)                                          F132b is CH.sub.2 ClCClF.sub.2 -                                               F131a is CH.sub.2 ClCCl.sub.2 F                                                TCE is CHC1═CCl.sub.2 -                                              

EXAMPLE 30 Disproportionation of F142b over MgF₂ /β-AlF₃ CH₃ CClF₂ →CH₃ CF₃ +CH₂ ═CCl₂

A vaporized sample of F142b mixed with nitrogen in a 1:2 molar ratio was passed over the MgF₂ /β-AlF₃ catalyst (15 mL), prepared as described in Example 3, at various temperatures. The contact time was 30 seconds for all runs. Product analysis by on line chromatography and mass spectrometry showed the following.

    ______________________________________                                                 Mole %                                                                 R.T. (°C.)                                                                        F143a        F142b   F1130a                                          ______________________________________                                         100       21.7         68.5    9.0                                             125       43.5         38.4    17.6                                            150       63.4         11.0    25.3                                            200       70.8         0.7     28.2                                            225       70.7         0.6     28.2                                            250       70.3         0.6     28.1                                            ______________________________________                                          Small quantities of other products were present                                F143a is CH.sub.3 CF.sub.3                                                     F142b is CH.sub.3 CClF.sub.2                                                   F1130a is CH.sub.2 ═CCl.sub.2                                        

EXAMPLE 31 Disproportionation of F31 over MgF₂ /β-AlF₃

A vaporized sample of F31 mxied with nitrogen in a 1:2 molar ratio was passed over the MgF₂ /β-AlF₃ catalyst (15), prepared as described in Example 3, at various temperatures. The contact time was 30 seconds for all runs. Product analysis showed the following.

    ______________________________________                                                  Mole %                                                                R.T. (°C.)                                                                         F32          F31    CH.sub.2 Cl.sub.2                               ______________________________________                                         150        22.9         46.5   30.6                                            175        37.7         11.6   50.6                                            200        37.9         11.1   51.0                                            250        36.9         13.1   49.9                                            300        36.7         15.2   48.0                                            350        35.2         17.0   47.7                                            ______________________________________                                    

EXAMPLE 32 Reaction of F114/F114a Mix and HCl over MgF₂ /β-AlF₃

A 10:1 molar ratio of HCl and a commercial F114 mix containing 89.1% F114 and 10.8% F114a were passed over the MgF₂ /β-AlF₃ catalyst (15 mL), prepared as described in Example 3, at various temperatures. Product analysis showed the following.

    ______________________________________                                                Mole %                                                                  R.T. (°C.)                                                                       F114     F114a   F113    113a PCE                                     ______________________________________                                         350      87.4     6.6     0.4     4.7  0.2                                     375      85.5     4.4     0.6     7.1  1.2                                     400      83.8     2.9     0.6     8.5  2.5                                     ______________________________________                                          F114 is CClF.sub.2 CClF.sub.2                                                  PCE is CCl.sub.2 ═CCl.sub.2                                          

Thus using the above catalyst the F114a is selectively degraded to provide a product enriched in F114. Small quantities of other products were present. 

What is claimed is:
 1. A process for changing the fluorine content of a halogenated hydrocarbon containing from 1 to 6 carbon atoms in the presence of a multiphase catalyst, characterized by:preparing a single phase solid catalyst precursor which has a structure that collapses at a temperature of about 600° C. or less and has the formula E_(u) E'_(1-u) Z_(v) (H₂ O)_(w) Y_(z) wherein E is at least one element selected from the group consisting of Group I through Group VIII metals of the Periodic Table, E' is at least one element other than the elements of E selected from the group consisting of Group I through Group VIII metals of the Periodic Table, Z is at least one anion selected from fluoride, chloride, bromide, oxide, and oxygen-containing groups which decompose at about 600° C. or less, Y is a cation which decomposes at about 600° C., or less, u is from 0.001 to 0.999, w is from 0 to about 20, z is from 0 to about 5, and v is selected to essentially balance the charge of said precursor; and producing said catalyst by heating said single phase solid catalyst precursor to about 600° C. or less to produce a multiphase composition wherein a phase containing E is homogeneously dispersed with a phase containing E', and at least when said precursor contains no fluoride, contacting said multiphase composition with a vaporizable fluorine-containing fluorinating compound at a temperature of from about 200° C. to 450° C.
 2. The process of claim 1 wherein said catalyst is a multiphase catalyst composition consisting essentially of fluorides of at least one divalent metal selected from the group consisting of Mn, Co, Zn, Mg and Cd and at least one trivalent metal selected from the group consisting of Al, Ga, Cr and V, wherein when Co is present another of said divalent metals is also present and Cr is not more than about 10 atom percent of said trivalent metals and is produced by heating a single phase fluoride composition of the formula MM'F₅ (H₂ O)₂ or the formula NH₄ MM'F₆ (H₂ O) where M is at least one divalent element selected from the group consisting of Mn, Co, Zn, Mg and Cd, provided that when Co is used another of said divalent elements is also used and M' is at least one trivalent element selected from the group consisting of Al, Ga, Cr and V, provided that Cr is not more than about 10 atom percent of said trivalent elements to a temperature sufficient to substantially remove H₂ O, and NH₄ F when NH₄ ⁺ is present, in said single phase fluoride composition.
 3. The process of claim 1 or claim 2 wherein a saturated or olefinic compound having the formula C_(n) H_(a) F_(b) X_(c) where n is an integer from 1 to 6, a is an integer from 0 to 12, b is an integer from 0 to 13, c is an integer from 0 to 13, provided that c is at least 1 when the compound is saturated, and each X is independently selected from Cl and Br, is reacted with HF in the vapor phase in the presence of said catalyst to increase the fluorine content of said compound.
 4. The process of claim 1 or claim 2 wherein a saturated compound having the formula C_(m) H_(d) F_(e) X_(f) where m is an integer from 1 to 6, d is an integer from 0 to 4, e is an integer from 1 to 13, f is an integer from 0 to 12, and each X is independently selected from Cl and Br, is reacted with HCl in the vapor phase in the presence of said catalyst to decrease the fluorine content of said compound.
 5. The process of claim 1 or claim 2 wherein a compound having the formula C_(p) H_(g) F_(h) Cl where p is an integer from 1 to 2, g is an integer from 1 to 3, and h is an integer from 1 to 4, undergoes disproportionation in the presence of said catalyst.
 6. The process of claim 2 wherein M comprises zinc and cobalt.
 7. The process of claim 2 wherein M comprises zinc and magnesium.
 8. The process of claim 2 wherein M' comprises aluminum and chromium.
 9. The process of claim 2 wherein M is from 1 to 99 atom percent Zn.
 10. The process of claim 2 wherein M is from 1 to 99 atom percent Co.
 11. The process of claim 2 wherein M' is from 1 to 99 atom percent Al.
 12. The process of claim 2 wherein M' is from 1 to 99 atom percent Ga.
 13. The process of claim 2 wherein the preparation of the multiphase catalyst composition comprises treatment with a vaporizable fluorine-containing fluorinating compound at elevated temperatures.
 14. The process of claim 2 wherein the multiphase catalyst composition comprises β-aluminum fluoride.
 15. The process of claim 14 wherein the preparation of the multiphase catalyst composition comprises treatment with a vaporizable fluorine-containing fluorinating compound at elevated temperatures. 